SACHEM selectively designs unique structure directing agents (SDA’s) and extenders from a range of highly pure and precise ammonium hydroxides and salts to meet complex performance standards in the industry. Keep in suitable, closed containers for disposal. Remove contact lenses, if present and easy to do. Remove contact lenses, if present and easy to do. Move containers from fire area if you can do it without risk. For electric vehicles or equipment, ERG Guide 147 (lithium ion batteries) or ERG Guide 138 (sodium batteries) should also be consulted. Chen. P310 Immediately call a POISON CENTER/doctor/\u2026. AMMONIUM HYDROXIDE reacts exothermically with acids. Revision Date: August 7, 2015. Item# 843690: Formula: NH 4 OH: Formula (search-friendly) NH4OH: Formula Weight: 35.05: CAS Number: 1336-21-6: Storage Code: White—corrosive: Resources (M)SDS - (Material) Safety Data Sheets (M)SDS - Ammonia Solution, Household . This is no longer a problem. Keep in a well-ventilated room. Avoid contact with skin and eyes. Get Teacher Tips and Exclusive Offers. Isn't it nonphysiological? (Thodos, G. Amer. /Conditions of bioassay not specified, Toxicity to daphnia and other aquatic invertebrates: LC50 Daphnia magna 0.66 mg/l/48 hr 22\u00b0C /Conditions of bioassay not specified, Toxicity to microorganisms: no data available, ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road, RID: Regulation concerning the International Carriage of Dangerous Goods by Rail, IMDG: International Maritime Dangerous Goods, IATA: International Air Transportation Association, IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home, HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm, IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/, eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en, CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple, ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp, ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg, Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp, ECHA - European Chemicals Agency, website: https://echa.europa.eu/. P280 Wear protective gloves/protective clothing/eye protection/face protection. Rinse mouth. Wuhan Haizheng Industry & Trade Development Co. Ltd, Shanghai Qinsheng Pharm Technology Co.,Ltd, For industry use only. Reacts with aqueous silver nitrate sodium hydroxide to give a black precipitate of silver nitride. It is obtained by dissolution of ammonia in water. Dike fire-control water for later disposal; do not scatter the material. LARGE FIRE: Dry chemical, CO2, alcohol-resistant foam or water spray. /Ammonia water: 28-29%/. Tetraethyl ammonium hydroxide. If breathing is difficult, give oxygen. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. Contact with molten substance may cause severe burns to skin and eyes. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. SDS #: 58.05. (ERG, 2016). FIRST-AID MEASURES Eyes Rinse with plenty of water for at least 15 minutes and seek medical attention immediately. Containers may explode when heated. First Aid Measures Eye Contact: If in eyes: Rinse cautiously with water for several minutes. Ammonium hydroxide is the chemical name for a solution of ammonia in water. Ammonium Hydroxide . Ammonium hydroxide Water Synonyms: Aqua ammonium; Ammonia solution 1336-21-6 7732-18-5 NH OH H O 35.05 18.00 5 - 70% 30-95% 4 2 SECTION 4 — FIRST AID MEASURES Call a POISON CENTER or physician if you feel unwell (P312). Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours). ALWAYS stay away from tanks engulfed in fire. Artificial respiration may be needed. Ammonium hydroxide is a weak base. Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Specialized Industrial Chemicals, 8F, Block C, No.3 Building, Zijin Plaza, No.701, Gudun Road, Hangzhou, Zhejiang 310030, China. If eye irritation persists: Get medical advice/attention immediately. .sds-ghs .header, .sds-ghs .content { font-family: 'times_new_roman', 'Times New Roman', sans-serif; } .avoid-page-break-inside { page-break-inside:avoid; } .sds-ghs h1, .sds-ghs h2, .sds-ghs h3, .sds-ghs h4, .sds-ghs h5, .sds-ghs h6 { font-weight: bold; } .sds-ghs h1 { text-align: left; font-size: 2em; margin: 0.67em 0; } .sds-ghs h2 { text-align: left; color: grey; font-size: 1.2em; margin: 0.83em 0; } .sds-ghs h3 { font-size: 1.17em; margin: 10px 0; } .sds-ghs h4 { /*text-align:center;*/ font-size: 1em; margin: 10px 0; } .sds-ghs h5 { font-style: italic; color: grey; font-size: 0.83em; margin: 10px 0; } .sds-ghs p { /*border: 1px solid blue;*/ color: black; line-height: 1; margin-bottom: 5px; } .sds-ghs hr { /*border: 1px solid blue;*/ color: black; margin: 0.5em 0; } .sds-ghs table { width: 100%; border-collapse: collapse; } .sds-ghs table td, .sds-ghs table th { border: 1px solid black; text-align: center; line-height: 1.5em; } .sds-ghs .subtitle { font-size: 12px; color: grey; text-align: right; } .sds-ghs .table-border-none th, .sds-ghs .table-border-none td { border: none; text-align: left; vertical-align: top; line-height: 1; } .sds-ghs .width-pc-70 { width: 70%; } .sds-ghs .width-pc-30 { width: 30%; } .sds-ghs .width-100 { width: 100px; } .sds-ghs .title-number { width: 50px; float: left; display: inline-block; } .sds-ghs .title-content { padding-left: 50px; display: block; } .sds-ghs .title { margin-right: -50px; border-top: 1px solid; } .sds-ghs .content { margin-left: 50px; margin-right: 50px; } .sds-ghs .m-t { margin-top: 15px; } .sds-ghs .text-left { text-align: left; } .sds-ghs h3 { margin-left: -50px; } .sds-ghs h3:before { clear: both; content: ''; }, Hazardous to the aquatic environment, short-term (Acute) - Category Acute 1, H314 Causes severe skin burns and eye damage. Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]: SMALL FIRE: Dry chemical, CO2 or water spray. (ERG, 2016), Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]: Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Safety glasses with side-shields conforming to EN166. Pick up and arrange disposal. A familiar example of ammonium hydroxide is household ammonia, which is a solution of 5-10% ammonia. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Inhalation Move casualty to fresh air and keep at rest. Effects of contact or inhalation may be delayed. Fire- Fighting Measures Extinguishing Media: Dry chemical, carbon dioxide, alcohol foam, water. Separated from food and feedstuffs. Ammonium hydroxide penetrates most rapidly of all alkali compounds. Cautiously neutralize spilled liquid with dilute acid such as dilute sulfuric acid. Continue rinsing. Ammonium Hydroxide, 3% 5. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Gloves must be inspected prior to use. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). 5. Avoid breathing vapours, mist or gas. Fresh air, rest. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. If inhaled: Remove victim to fresh air and keep at rest in a position comfortable for breathing (P304+P340). Although the name ammonium hydroxide suggests an alkali with composition [NH 4 +][OH −], it is actually impossible to isolate samples of NH 4 OH. Ensure adequate ventilation. Household ammonia water contains about 10% ammonia by weight. Refer for medical attention . CAS 7732-18-5 7664-41-7 7664-41-7 AMMONIUM HYDROXIDE 26 DEGREE BAUME water ammonia (sara 302/313) (cercla) ammonia (sara 302/313) (cercla) msds toxicity property Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-9403 (ERG, 2016). The corneal epithelium and endothelium provide a barrier to water soluble substances while the stroma is a barrier to lipid soluble substances. Cool containers with flooding quantities of water until well after fire is out. Ammonium Hydroxide Solution 1 M, 1 L. Flinn Lab Chemicals, Your Safer Source for Science. Visit Flinn Canada. Avoid dust formation. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials. Aqueous ammonia is used in the laboratory most often as a complexant and base in inorganic analysis. Evacuate danger area! chemBlink provides samples of SDS, Safety Data Sheets, for Ammonium hydroxide, CAS 1336-21-6 Such a precipitate can explode on stirring [MCA Case History 1554 1968]. Male rats gavaged with 1000 umol (15)N-ammonium chloride each day for 5 days excreted low, but significant amounts of excess (15)N-NO3- in urine on the 5 days of treatment & on the 5 subsequent days.An in vitro chemical model system was used to demonstrate that oxidation of ammonia to NO3- by the hydroxyl radical at physiological pH is chemically feasible. Special Protective Equipment: Fire fighters should use self-contained breathing apparatus and protective clothing. Ammonium hydroxide solutions are used as cleansers and detergents to remove vegetable stains, grease, dirt, proteins, and other accretions from clothing, glass, and ceramics. Continue rinsing. SECTION 1 — CHEMICAL PRODUCT AND COMPANY IDENTIFICATION. Injuries are caused by neutral organic, acid, and alkali compounds. Inhalation Move casualty to fresh air and keep at rest. Isn't buffering capacity low? Can also dissolve silver residues. LC11210 LC11210: Ammonium molybdate, 4.0 - 7.5%: LC11220 LC11220: Ammonium molybdate, 4.0 - 7.5%: LC26600 Ammonium Hydroxide, 14.5 M, Strong Ammonia Solution, ACS Grade, 500 mL Item #844010 $14.95 Quick View Ammonium Hydroxide, 14.5 M, Plastic-Coated Safety Bottle, ACS Grade, 2.5 … Calcium hydroxide, sodium hydroxide, and ammonium hydroxide are most often responsible for alkali burns. Do NOT let this chemical enter the environment. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Alkali compounds cause most severe injuries depending on the hydroxyl ion concentration and the cation. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Although the pH is 2 units from either pK, both ions buffer. The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Calcium hydroxide, sodium hydroxide, and ammonium hydroxide are most often responsible for alkali burns. Consult an expert! FIRST-AID MEASURES Eyes Rinse with plenty of water for at least 15 minutes and seek medical attention immediately. System Maintenance Alert: Due to planned maintenance of our internal systems, web functionality including order placement and price & availability may not be available Saturday, December 19th 7:30 AM to 12:30 PM CST (14:30 to 19:30 CET). For personal protection see section 8. Tetramethylammonium hydroxide (TMAH or TMAOH) is a quaternary ammonium salt with the molecular formula N(CH 3) 4 + OH −.It is commonly encountered as concentrated solutions in water or methanol.The solid and solutions are colorless, or yellowish if impure. Avoid any skin contact. pH= 11.6 (1.0 N solution); 11.1 (0.1 N solution); 10.6 (0.01 N solution), ADR/RID: AMMONIA SOLUTION, relative density between 0.880 and 0.957 at 15 \u00b0C in water, with more than 10% but not more than 35% ammonia, IMDG: AMMONIA SOLUTION, relative density between 0.880 and 0.957 at 15 \u00b0C in water, with more than 10% but not more than 35% ammonia, IATA: AMMONIA SOLUTION, relative density between 0.880 and 0.957 at 15 \u00b0C in water, with more than 10% but not more than 35% ammonia, Toxicity to fish: LC50 Lepomis macrochirus (bluegill) 0.024-0.093 mg/l/48 hr. Shop a large selection of products and learn more about Ammonium Hydroxide Solution, 14.8M. Well closed. 77-98-5. Fire Hazards (Chemical): Not flammable. Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Trimethyladamantylammonium Hydroxide is a structure directing agent for SSZ-13 Chabazite Zeolite. Ratings & Reviews. For precautions see section 2.2. Wear dust mask when handling large quantities. Handle with gloves. First Aid Measures IF INHALED: Immediately remove person to fresh air and keep comfortable for breathing. eg. Show this safety data sheet to the doctor in attendance. Cool. It is a clear liquid with a distinctive pungent, fishy odor. Do NOT induce vomiting. Reacts extremely violently with dimethyl sulfate [NFPA 491M 1991]. P301+P330+P331 IF SWALLOWED: Rinse mouth. UNII-RA8VU41B1F. P321 Specific treatment (see ... on this label). Ammonium Hydroxide 8-9 1336-21-6 215-647-6 H 5 NO 35.05 g/mol Water Balance 7732-18-5 231-791-2 H 2 O 18.00 g/mol 4. Evacuate personnel to safe areas. Refer for medical attention. Do NOT induce vomiting. Search results for ammonium hydroxide at Sigma-Aldrich. (Ammonium hydroxide) 12 ECOLOGICAL INFORMATION Ammonium hydroxide (1336-21-6) [20-30%] Information on ecological effects Toxicity: Toxicity to fish mortality NOEC - Oncorhynchus tshawytscha - 3.5 mg/l - 3.0 d (Ammonium: hydroxide) Toxicity to daphnia and LC50 - Daphnia magna (Water flea) - 32 mg/l - 50 h (Ammonium hydroxide): Wash away remainder with plenty of water. Do not discharge to sewer systems. P363 Wash contaminated clothing before reuse. Do not get water inside containers. See Chemical Dangers. J., 1964, 10, 274.). Tai`an Ming Chen Chemical Import&Export Co.,Ltd. Stable under recommended storage conditions. Use the molar mass of NH4OH. See Notes.Keep cool in strong glass, plastic, or rubber stoppered bottles not completely filled. Óï7ûýæñ_§W_>6§?×w«u½_mÖß}Ǿ? Ammonium Hydroxide Solution 1 M or Less Flinn Scientific, Inc. P.O. It can be denoted by the symbols NH 3 (aq). Ammonium hydroxide solution Volumetric, 5.0 M NH4OH (5.0N), CAS Number: 7732-18-5, 1336-21-6,(318612 Fluka).Shop now or request a quote. FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. P260 Do not breathe dust/fume/gas/mist/vapours/spray. Ammonium Hydroxide 28-30 1336-21-6 215-647-6 H 5 NO 35.05 g/mol Water Balance 7732-18-5 231-791-2 H 2 O 18.00 g/mol 4. Ammonium hydroxide is a colorless, alkaline liquid with a pungent ammonia odor. "Ammonium acetate as a neutral buffered standard", C.J. Rinse skin with water [or shower]. CAS 7664-41-7 7732-18-5 SPOTLESS WHITE AMMONIUM HYDROXIDE ammonia (sara iii) water msds toxicity property Ammonia, Anhydrous: CAS # 7664-41-7; Water: CAS# 7732-18-5 AMMONIUM HYDROXIDE HEALTH-3 FLAMMABILITY 1 PHYSICAL HAZARD 0 PERSONAL PROTECTION H. Revision Date: November 1, 2018 Ammonium Hydroxide Page 3 of 9 Section 4. If not Wash hands before breaks and at the end of workday. CAUSTIC LIQ FORMS EXPLOSIVE CMPD WITH MANY HEAVY METALS SUCH AS SILVER, LEAD, ZINC, & THEIR SALTS, ESPECIALLY HALIDE SALTS. Use personal protective equipment. To get a specific concentration you will need to calculate the number of moles required and covert this to a mass. You will mix NH4OH with water. Tetraethylammonium hydroxide. Inst. Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]: TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Tetrabutyl Ammonium Hydroxide 2052-49-5 Suppliers,provide Tetrabutyl Ammonium Hydroxide 2052-49-5 product and the products related with China (Mainland) Tetrabutyl Ammonium Hydroxide 2052-49-5 JINHUA HUAYI CHEMICAL CO., LTD. China (Mainland) ... COA, SDS, price, delivery time, payment terms and other information you need. When heated to decomposition it emits ammonia and nitroxides. Engrs. Features & Specs. Fire may produce irritating, corrosive and/or toxic gases. 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